ΓΌ Purification
of Colloids:
The colloidal
solution prepared contains excess amount of electrolyte and some other soluble
impurities. Even though small amount of electrolyte is required for the
stability of colloid, large amount may cause precipitation. The process of
reducing the concentration of electrolyte and other impurities is known as
purification of colloids. Some methods used for purification are:
Γ Dialysis:
The
process of removing the impurities from a sol by means of diffusion through a
semi permeable membrane is called dialysis.
Γ Electrodialysis:
When
dialysis process is accelerated by the application of a potential difference across
the membrane, so ions migrate faster than the colloids.
Γ Ultra-filtration:
Purification
of colloidal solution using special filter paper called ultra filters (filter
paper which is impregnated with gelatin or collodion followed by hardening in
formaldehyde). Colloidion
is a 4% nitrocellulose soln in alcohol and ether.
ΓΌ Properties
of colloids:
Γ Heterogeneous
nature: Colloids are heterogeneous in nature and consists of two phases, the dispersed phase and
the dispersion medium.
Γ Visibility: The particles are too small to be
seen with naked eye but become visible when viewed through ultra-microscope due
to scattering of light by them.
Γ Surface
tension and Viscosity: The surface tension and viscosity of
lyophobic sols are not very different from that of dispersed medium. But,
lyophillic sols show higher
viscosity and lower surface tension in comparison to the dispersion medium.
Γ Tyndall
Effect: When
a light beam is passed through a colloidal solution, we can see the path of the
light beam. This phenomenon is known as Tyndall effect. It is due to the
scattering of light beam by the colloidal particles. The visible path is called
tyndall cone.
Γ Brownian movement: Zig-zag movement of colloidal
particles due to collision between particles of dispersed phase & dispersion
medium, responsible for stability of colloids.
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