ΓΌ Oxoacids
of Halogens: The term
oxoacid now refers to a compound which contains oxygen, at least one other
element, and at least one hydrogen bound to oxygen.
· Fluorine forms only one oxoacid HOF
(Fluoric (I) acid or hypofluorous acid) dueto high electronegativity.
· The other halogens form several
oxoacids like Hypohalous acid (HOX), halous acid (HOXO), halic acid (HOXO2)
and perhalic acid (HOXO3). They are stable only in aqueous solutions
or in the form of their salts.
· Chlorine forms 4 types of
oxoacids – hypochlorous acid (HOCl), Chlorous acid (HOClO or HClO2),
Choric acid (HOClO2 or HClO3) and perchloric acid (HOClO3
or HClO4). The structures of them are:
·
Acid strength: HOCl < HClO2
< HClO3 < HClO4
Reason: HClO4 → H+
+ ClO4-
most
stable
·
Acid strength: HOF > HOCl
> HOBr > HOI
This is because Fluorine is most
electronegative.
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