Acids, Bases and Salts Part - 3 | Class - 10th




BASES:
Substances which change red litmus solution blue are called bases. They are bitter in taste.
They releases hydroxide ions (OH-) when dissolved in water. They have a soapy touch (e.g. Washing soda, caustic soda and caustic potash).

CLASSIFICATION OF BASES:
Ø    Based on Ionisation:
v    Strong Bases: These are bases which ionise completely in aqueous solution eg. NaOH, KOH.
v    Weak bases: These are bases which ionise partially in aqueous solution eg. NH4OH, Ca(OH)2.

Ø  Based on their Acidity:
v    Monoacidic Base: It is a base which ionises in water to give one hydroxide ion per molecule eg. NaOH, KOH.
v    Diacidic Base: It is a base which ionises in water to give two hydroxide ions per molecule eg.  Ca(OH)2, Mg(OH)2.
v Triacidic Base: It is a base which ionises in water to give three hydroxide ions per molecule eg. Al(OH)3, Fe(OH)3.

Ø  Based on the Concentration:
Depending upon the amount of water added in a base, bases are classified as concentrated and dilute Bases.
v    Concentrated alkali: It is an alkali having a relatively high percentage of alkali in its aqueous solution.
v    Dilute alkali: It is an alkali having a relatively low percentage of alkali in its aqueous solution.

Chemical properties of Base:
Ø    Reaction of Base with Metals:
When alkali (base) reacts with metal, it produces salt and hydrogen gas.
Alkali + Metal Salt + Hydrogen
v    Sodium aluminate and hydrogen gas are formed when sodium hydroxide reacts with aluminium metal.
             2NaOH + 2Al + 2H2O 2NaAlO2 + 2H2
v    Sodium hydroxide gives hydrogen gas and sodium zincate when reacts with zinc metal. 
             2NaOH + Zn Na2ZnO2 + H2

Ø    Reaction of Non-Metallic Oxides with Base:
Non- metallic oxides react with base to produce Salt and Water
 Non-metallic oxide + Base → Salt + Water
v    Ca(OH)2 + CO2 → CaCO3 + H2O
F    Non Metallic oxides are said to be acidic in nature because on reacting with a base they produce Salt and Water.

Ø    Action of Alkalis/Base with Ammonium Salts:
 Alkalis combine with ammonium salts to liberate ammonia.
 Alkali + Ammonium salt     Salt  + Water + Ammonia
v    Ca(OH)2 + NH4Cl    CaCl2 + H2O + NH3

USES OF BASES:
Ø    Magnesium hydroxide is used as a medicine for stomach troubles.
Ø    Ammonium hydroxide is used to remove grease stains from clothes.
Ø    Sodium hydroxide is used in the manufacture of soap.
Ø    Calcium hydroxide is used in white washing the buildings.

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