BASES:
Substances which change
red litmus solution blue are
called bases. They are bitter in taste.
They
releases hydroxide ions
(OH-) when dissolved in water. They have a soapy touch (e.g.
Washing soda, caustic soda and caustic potash).
CLASSIFICATION
OF BASES:
Ø
Based
on Ionisation:
v
Strong Bases: These are bases which ionise completely in
aqueous solution eg. NaOH, KOH.
v
Weak bases: These are bases which ionise partially in
aqueous solution eg. NH4OH, Ca(OH)2.
Ø Based
on their Acidity:
v Monoacidic
Base: It is a base
which ionises in water to
give one hydroxide ion per molecule eg. NaOH, KOH.
v Diacidic
Base: It is a base
which ionises in water to give
two hydroxide ions per molecule
eg. Ca(OH)2, Mg(OH)2.
v Triacidic
Base: It is a base
which ionises in water to give
three hydroxide ions per molecule
eg. Al(OH)3, Fe(OH)3.
Ø Based
on the Concentration:
Depending
upon the amount of water added in a base, bases are classified as concentrated
and dilute Bases.
v
Concentrated alkali: It is
an alkali having a
relatively high percentage of alkali in its aqueous solution.
v
Dilute alkali: It is an alkali having a relatively low
percentage of alkali in its aqueous solution.
Chemical properties of Base:
Ø Reaction of Base with Metals:
When alkali (base) reacts
with metal, it produces salt
and hydrogen gas.
Alkali + Metal →
Salt + Hydrogen
v Sodium aluminate and hydrogen gas
are formed when sodium hydroxide reacts with aluminium
metal.
2NaOH
+ 2Al + 2H2O → 2NaAlO2 + 2H2
v Sodium hydroxide gives hydrogen gas
and sodium zincate when reacts with zinc metal.
2NaOH + Zn → Na2ZnO2 + H2
2NaOH + Zn → Na2ZnO2 + H2
Ø
Reaction
of Non-Metallic Oxides with Base:
Non- metallic oxides react with base to produce Salt and Water
Non-metallic oxide + Base → Salt + Water
v Ca(OH)2 + CO2
→ CaCO3 + H2O
F
Non Metallic oxides are said to be acidic
in nature because on reacting with a base they produce Salt and Water.
Ø
Action
of Alkalis/Base with Ammonium Salts:
Alkalis combine with ammonium salts to
liberate ammonia.
Alkali + Ammonium salt → Salt + Water + Ammonia
v Ca(OH)2 + NH4Cl → CaCl2
+ H2O + NH3
USES OF BASES:
Ø Magnesium hydroxide is used as a medicine for stomach troubles.
Ø Ammonium hydroxide is used to remove grease stains from clothes.
Ø Sodium hydroxide is used in the manufacture of soap.
Ø Calcium hydroxide is used in white washing the buildings.

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